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The High Court said it would also try the former coach of the women's national team, Jorge Vilda, the team's current sporting director, Albert Luque, and the federation's head of marketing, Ruben Rivera.
World champions Spanish women's football team were named Team of the Year, the first female squad to win the award.
Prosecutor Marta Durantez charged Rubiales with one count of sexual assault and one of coercion for his alleged actions in the aftermath of the kiss, offences carrying jail terms of one year and 18 months, respectively.
Infantino's pre-tax base salary payment rose by more than 500,000 Swiss francs ($565,000) last year to reach more than 2.46 million Swiss francs ($2.78 million).
Prosecutors and lawyers can still present their arguments, after which the court will decide whether and when to call the trial. Up until now, the case has been handled by an investigative judge.
Hermoso spent around two-and-a-half hours speaking behind closed doors to investigating judge Francisco de Jorge, who is examining evidence including television footage before deciding whether to approve charges and advance the case to trial.
The decision was reached around 5 am after more than seven hours of meetings.
After most of Spain's World Cup-winning squad were selected for upcoming games earlier on Monday, the players said they would continue their boycott, which came after Rubiales kissed Hermoso on the lips during the trophy presentation ceremony.
The order prevents Rubiales trying to contact Hermoso or coming within 200 metres of her.
Rubiales announced his resignation in a statement in which he said his position had become untenable, with the Spanish Football Federation later confirming he had sent a resignation letter to acting president Pedro Rocha.
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