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WADA said the tribunal's finding of 'no fault or negligence' on Sinner's part was incorrect under the applicable rules, and it would seek 'a period of ineligibility of between one and two years' for the Australian Open and US Open champion.
For 23-year-old Sinner, it was a 55th match win of the season and sixth title.
The Italian defeated American Alex Michelsen 6-4 6-0 6-2.
Djokovic, who has not competed since winning the gold medal at the Paris Olympics, will begin against a qualifier and is expected to meet Andrey Rublev in the quarterfinals and fourth seed Alexander Zverev in the semis.
The tribunal convened by Sport Resolutions accepted the Australian Open champion's explanation that the anabolic agent clostebol entered his system through massages and sports therapy.
Jasmine Paolini blazed past American Emma Navarro 6-2 6-1 to become the first Italian woman to make the Wimbledon semifinals.
Taylor Fritz toppled Alexander Zverev with a 4-6 6-7(4) 6-4 7-6(3) 6-3 victory to reach the quarterfinals.
World number one Jannik Sinner quelled the challenge of big-serving 14th seed Ben Shelton with a 6-2 6-4 7-6(9) victory.
Carlos Alcaraz reached his maiden French Open final with a 2-6 6-3 3-6 6-4 6-3 win over Jannik Sinner before Alexander Zverev also recovered from a slow start on Friday to beat Casper Ruud.
Second seed Sinner kept his hopes of taking Djokovic's top ranking alive with a battling 2-6 6-3 6-2 6-1 win over local favourite Corentin Moutet.
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