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Raina and Gorgodze defeated Zadoinov Bolsova and Aliona Juvan 6-4, 3-6, 10-6 in the final of the $100,000 hard court event at the Habtoor Grand Beach Resort and Spa in Dubai.
Along with the award, the 33-year-old also received a cheque for $2,000 to be donated to a charity and she opted to help with relief during the ongoing coronavirus crisis.
Sania is the nominee from the Asia/Oceania Zone along with Indonesia's Priska Madelyn Nugroho.
Kristina Mladenovic and Caroline Garcia combined for the decisive point, grinding down Ash Barty and Sam Stosur 6-4, 6-3 in the doubles to seal France's third title in the team event.
On a day of scorching heat, France struck the early blow when Kristina Mladenovic thrashed Ajla Tomljanovic 6-1, 6-1 but the terrier-like Barty wrested back the momentum with her 6-0, 6-0 humiliation of Garcia.
Katerina Siniakova and veteran Barbora Strycova powered the Czech Republic to the verge of another Fed Cup title in the final against defending champions the United States.